El sitio web de la UCLM utiliza cookies propias y de terceros con fines técnicos y de análisis, pero no recaba ni cede datos de carácter personal de los usuarios. Sin embargo, puede haber enlaces a sitios web de terceros, con políticas de cookies distintas a la de la UCLM, que usted podrá aceptar o no cuando acceda a ellos.

Puede obtener más información en la Política de cookies. Aceptar

English
  1. Inicio
  2. Química organometálica y catálisis homogénea (QUIMORCA)
  3. Química de Coordinación y Organometálica Orientada a la Catálisis (COMCat)
  4. Publicaciones

Publicaciones

2010-presente
  1. Alberto Ramos, Fernando Carrillo-Hermosilla, Rafael Fernández-Galán, David Elorriaga, Jesús Naranjo, Antonio Antiñolo, and Daniel García-Vivó. ZnEt2 as a Precatalyst for the Addition of Alcohols to Carbodiimides.Organometallics, 2022, 41, 21, 2949–2957. DOI: 10.1021/acs.organomet.2c00372
  2. Fernando Carrillo-Hermosilla, Rafael Fernández-Galán, Alberto Ramos and David Elorriaga. Guanidinates as Alternative Ligands for Organometallic Complexes.Molecules 2022, 27, 5962-5993. DOI: 10.3390/molecules27185962
  3. David Elorriaga, Fernando Carrillo-Hermosilla, Blanca Parra-Cadenas, Antonio Antiñolo, Joaquin García-Álvarez. Aerobic/Room-Temperature-Compatible s-Block Organometallic Chemistry in Neat Conditions: A Missing Synthetic Tool for the Selective Conversion of Nitriles into Asymmetric Alcohols. ChemSusChem 2022, 15, e202201348. DOI: 10.1002/cssc.202201348
  4. María Luisa Valenzuela, Desmond MacLeod-Carey, Cristian Soto Marfull, José León-Baeza, Javier Martínez, Antonio Antiñolo, Fernando Carrillo. Synthesis and Theoretical Study of New Guanylated Cyclophosphazenes and Their Use in the CO2 Fixation into Styrene Carbonate. J. Inorg. Organomet. Polym. 2022, 32, 1724–1735. DOI: 10.1007/s10904-022-02264-6.
  5. D. Elorriaga, B. Parra-Cadenas, A. Antiñolo, F. Carrillo-Hermosilla, J. García-Álvarez. Combination of air/moisture/ambient temperature compatible organolithium chemistry with sustainable solvents: selective and efficient synthesis of guanidines and amidines. Green Chemistry, 2022, 24, 800-812. 10.1039/D1GC03393J
  6. P. J. Pacheco-Liñán, C. Alonso-Moreno, F. Carrillo-Hermosilla, A. Garzón-Ruiz, C. Martín, C. Sáez, J. Albaladejo, I. Bravo. Novel Fluorescence Guanidine Molecules for Selective Sulfate Anion Detection in Water Complex Samples over a Wide pH Range. ACS Sens. 2021, 6, 3224–3233. 10.1021/acssensors.1c00876
  7. Y. Rios Yepes, Á. Mesías-Salazar, A. Becerra, C. G. Daniliuc, A. Ramos, R. Fernández-Galán, A. Rodríguez-Diéguez, A. Antiñolo, F. Carrillo-Hermosilla, R. S. Rojas. Mono- and Dinuclear Asymmetric Aluminum Guanidinates for the Catalytic CO2 Fixation into Cyclic Carbonates. Organometallics 2021, 40, 2859-2869. DOI: 10.1021/acs.organomet.1c00319
  8. R. S. Rojas, K. Muñoz-Becerra, A. Toro-Labbé, A. Mesías-Salazar, I. Martínez, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, A. Ramos, C. G. Daniliuc, New guanidine-borane adducts: An experimental and theoretical approach. Inorg. Chim. Acta 2021, 518, 120217. DOI: 10.1016/j.ica.2020.120217
  9. E. Huergo, R. Fernández-Galán, A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, A. Rodríguez-Diéguez, D. García-Vivó. Reactivity of N-Phosphinoguanidines of the Formula (HNR)(Ph2PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from N-Phosphinoguanidinates to Phosphinimine-Amidinates. Inorg. Chem. 2020, 59, 15262-15275. DOI: 10.1021/acs.inorgchem.0c02224
  10. A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán. Ph2PCH2CH2B(C8H14) and Its Formaldehyde Adduct as Catalysts for the Reduction of CO2 with Hydroboranes. Inorg. Chem. 2020, 59, 9998-10012. DOI: 10.1021/acs.inorgchem.0c01152
  11. Y. Rios Yepes, J. Martínez, H. Rangel Sánchez, C. Quintero, M. C. Ortega-Alfaro, J. G. López-Cortés, C. G. Daniliuc, A. Antiñolo, A. Ramos, R. S. Rojas, R. Aluminum complexes with new non-symmetric ferrocenyl amidine ligands and their application in CO2 transformation into cyclic carbonates. Dalton Trans., 2020, 49, 1124-1134. DOI: 10.1039/C9DT03808F
  12. A. Mesias-Salazar, O. S. Trofymchuk, C. G. Daniliuc, A. Antiñolo, F. Carrillo-Hermosilla, F. M. Nachtigall, L. S. Santos, R. S. Rojas. Copper (II) as catalyst for intramolecular cyclization and oxidation of (1,4-phenylene)bisguanidines to benzodiimidazole-diylidenes. J. Catal., 2020, 382, 150-154. DOI: https://doi.org/10.1016/j.jcat.2019.12.002
  13. A. Antiñolo, S. García-Yuste, I. López-Solera, A. Otero, M. T. Tercero-Morales, F. Carrillo-Hermosilla. Reactivity studies on a trihydride niobocene complex towards α,β-Unsaturated carboxylic acids. J. Organomet. Chem., 2019, 897, 120-129. DOI: 10.1016/j.jorganchem.2019.06.006
  14. Á. Mesías-Salazar, J. Martínez, R. S. Rojas, F. Carrillo-Hermosilla, A. Ramos, R. Fernández-Galán, A. Antiñolo. Aromatic guanidines as highly active binary catalytic systems for the fixation of CO2 into cyclic carbonates under mild conditions. Catal. Sci. Technol., 2019, 9, 3879-3886. DOI: 10.1039/c9cy00667b
  15. A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, D. García-Vivó. 9-Borabicyclo[3.3.1]nonane: a metal-free catalyst for the hydroboration of carbodiimides, Chem. Commun., 2019, 55, 3073-3076. DOI: 10.1039/C9CC00593E
  16. R. Fernández-Galán, A. Ramos, E. Huergo, A. Antiñolo, F. Carrillo-Hermosilla, A. Rodríguez-Diéguez, D. García-Vivó. Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds. Chem. Commun., 2019, 55, 2809-2812. DOI: 10.1039/C9CC00432G
  17. A. Antiñolo, M. A. Esteruelas, C. García-Yebra, J. Martín, E. Oñate, A. Ramos. Reactions of an Osmium(IV)-Hydroxo Complex with Amino-Boranes: Formation of Boroxide Derivatives. Organometallics, 2019, 38, 310-318. DOI: 10.1021/acs.organomet.8b00727
  18. S. Moreno, A. Ramos, F. Carrillo-Hermosilla, A. Rodríguez-Diéguez, D. García-Vivó, R. Fernández-Galán, A. Antiñolo. Selective Three-Component Coupling for CO2 Chemical Fixation to Boron Guanidinato Compounds Inorg. Chem., 2018, 57, 8404-8413. DOI: 10.1021/acs.inorgchem.8b01068
  19. A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Gálan, A. Rodríguez-Diéguez, D. García-Vivó. Carbodiimides as catalysts for the reduction of CO2 with boranes. Chem. Commun., 2018, 54, 4700-4703. DOI: 10.1039/C8CC02139B
  20. P. J. Pacheco-Liñán, J. Fernández-Sainz, I. Bravo, A. Garzón-Ruiz, C. Alonso-Moreno, F. Carrillo-Hermosilla, A. Antiñolo, José Albaladejo. Guanidine Substitutions in Naphthyl Systems to Allow a Controlled Excited-State Intermolecular Proton Transfer: Tuning Photophysical Properties in Aqueous Solution. J. Phys. Chem. C, 2018, 122, 9363-9373. DOI: 10.1021/acs.jpcc.8b02576
  21. A. Martínez, S. Moreno-Blázquez, A. Rodríguez-Diéguez, A. Ramos, R. Fernández-Galán, A. Antiñolo, F. Carrillo-Hermosilla. Simple ZnEt2 as a catalyst in carbodiimide hydroalkynylation: structural and mechanistic studies. Dalton Trans., 2017, 46, 12923-12934. DOI: 10.1039/C7DT02700A
  22. A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, M. P. Montero-Rama, E. Villaseñor, A. Rodríguez-Diéguez, D. García-Vivó. Insertion reactions of small unsaturated molecules in the N-B bonds of boron guanidinates. Dalton Trans., 2017, 46, 10281-10299. DOI: 10.1039/C7DT02081C
  23. I. Posadas, C. Alonso-Moreno, I. Bravo, F. Carrillo-Hermosilla, A. Garzón, N. Villaseca, I. López-Solera, J. Albaladejo, V. Ceña. Synthesis, Characterization, DNA Interactions and Antiproliferative Activity on Glioblastoma of Iminopyridine Platinum (II) Chelate Complexes. J. Inorg. Biochem., 2017, 168, 46-54. DOI: 10.1016/j.jinorgbio.2016.11.032
  24. A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, M. P. Montero-Rama, A. Ramos, E. Villaseñor, R. S. Rojas, A. Rodríguez-Diéguez. Dialkylboron guanidinates: syntheses, structures and carbodiimide de-insertion reactions. Dalton Trans., 2016, 45, 15350-15363. DOI: 10.1039/C6DT02913B
  25. M. De Tullio, A. Hernán-Gómez, Z. Livingstone, W. Clegg, A. R. Kennedy, R. W. Harrington, A. Antiñolo, A. Martínez, F. Carrillo-Hermosilla, E. Hevia. Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines. Chem. Eur. J., 2016, 22, 17646-17656. DOI: 10.1002/chem.201602906
  26. A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, J. Martínez-Ferrer, C. Alonso-Moreno, I. Bravo, S. Moreno-Blázquez, M. Salgado, E. Villaseñor, J. Albaladejo. Tris(pentafluorophenyl)borane as an efficient catalyst in the guanylation reaction of amines. Dalton Trans., 2016, 45, 10717-10729. DOI: 10.1039/C6DT01237J
  27. Iván Bravo, Carlos Alonso-Moreno, Inmaculada Posadas, José Albaladejo, Fernando Carrillo-Hermosilla, Valentín Ceña, Andres Garzón, Isabel López-Solera, Laura Romero-Castillo. Phenyl-Guanidine Derivatives as Potential Therapeutic Agents for Glioblastoma Multiforme: Catalytic Syntheses, Cytotoxic Effects and DNA Affinity. RSC Advances, 2016, 6, 8267-8276. DOI: 10.1039/C5RA17920C
  28. J. Francos, P. J. González-Liste, L. Menéndez-Rodríguez, P. Crochet, V. Cadierno, J. Borge, A. Antiñolo, R. Fernández-Galán, F. Carrillo-Hermosilla. Half-Sandwich Guanidinate-Osmium(II) Complexes: Synthesis and Application in the Selective Dehydration of Aldoximes. Eur. J. Inorg. Chem., 2016, 393-402. DOI: 10.1002/ejic.201501221
  29. D. Nieto, S. Bruña, A. M. González-Vadillo, J. Perles, F. Carrillo-Hermosilla, A. Antiñolo, J. M. Padrón, G. B. Plata, I. Cuadrado. Catalytically Generated Ferrocene-Containing Guanidines as Efficient Precursors for New Redox-Active Heterometallic Platinum(II) Complexes with Anticancer Activity. Organometallics, 2015, 34, 5407-5417. DOI: 10.1021/acs.organomet.5b00751
  30. I. Bravo, C. Alonso-Moreno, F. Carrillo-Hermosilla, I. López-Solera, A. Antiñolo, J. Albaladejo. Toward the Prediction of Activity in the Ethylene Polymerisation of ansa-Bis(indenyl) Zirconocenes: Effect of the Stereochemistry and Hydrogenation of the Indenyl Moiety. ChemPlusChem, 2015, 80, 963-972. DOI: 10.1002/cplu.201500008
  31. L. Menéndez-Rodrı́guez, E. Tomás-Mendivil, J. Francos, P. Crochet, V. Cadierno, A. Antiñolo, R. Fernández-Galán,F. Carrillo-Hermosilla. Reactivity of the Dimer [{RuCl(μ-Cl)(η3:η3-C10H16)}2] (C10H16= 2,7-Dimethylocta-2,6-diene-1,8-diyl) toward Guanidines: Access to Ruthenium(IV) and Ruthenium(II) Guanidinate Complexes. Organometallics, 2015, 34, 2796-2809. DOI: 10.1021/acs.organomet.5b00070
  32. A. Antiñolo, S. García Yuste, A. Otero, A. Espinosa. Unusual Mechanism for the Reaction of a Niobocene HydrideComplex with Activated Alkynes. Experimental and DFT Studies. Organometallics, 2015, 34, 2695-2698. DOI: 10.1021/om5010989
  33. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, R. Fernández-Galán, E. Villaseñor. Mixed amido-/imido-/guanidinato niobium complexes: synthesis and the effect of ligands on insertion reactions. Dalton Trans., 2014, 43, 17434-17444. DOI: 10.1039/c4dt01975j
  34. A.R. Cabrera, E. Villaseñor, F. Werlinger, R. S. Rojas, M. Valderrama, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán. Grafting of the zirconium complexes [Zr(η5-C5H5){NC-amidine}Cl2] and [Zr(η5-C5H5)(NC-NacNac)Cl2] and the study of their behavior in ethylene polymerization. J. Mol. Cat. A., 391, 130-138. DOI: 10.1016/j.molcata.2014.04.017
  35. C. Alonso-Moreno, A. Antiñolo, F. Carrillo-Hermosilla, A. Otero. Guanidines: from classical approaches to efficient catalytic syntheses. Chem. Soc. Rev., 2014, 43, 3406-3425. DOI: 10.1039/c4cs00013g
  36. R. Fernández-Galán, J.-A. Navarro, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, E. Villaseñor. Preparation and Structural Studies of Non-Symmetric Guanidinate-Supported Zirconium Complexes. Aust. J. Chem., 2014, 67, 1063. DOI: 10.1071/ch14181
  37. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, R. Fernández-Galán, E. Villaseñor. Unexpected mild C-N bond cleavage mediated by guanidine coordination to a niobium iminocarbamoyl complex. Chem. Commun., 2013, 49, 8701-8703. DOI: 10.1039/c3cc44952a
  38. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, F. J. Suárez, I. López-Solera, R. Fernández-Galán, E. Villaseñor. Asymmetric niobium guanidinates as intermediates in the catalytic guanylation of amines. Dalton Trans., 2013, 42, 8223-8230. DOI: 10.1039/C3DT50477H
  39. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, R. Fernández-Galán, A. Serrano, E. Villaseñor. Synthesis, Characterization and Reactivity of New Dinuclear Guanidinate Diimidoniobium Complexes. Eur. J. Inorg. Chem., 2013, 2940-2946. DOI: 10.1002/ejic.201300025
  40. E. Villaseñor, R. Gutierrez-Gonzalez, F. Carrillo-Hermosilla, R. Fernández-Galán, I. López-Solera, A. R. Fernández-Pacheco, A. Antiñolo. Neutral Dimethylzirconocene Complexes as Initiators for the Ring-Opening Polymerization of ϵ-Caprolactone. Eur. J. Inorg. Chem., 2013, 2013, 1184-1196. DOI: 10.1002/ejic.201201096
  41. A. Antiñolo, J.-C. Pérez-Flores, M. J. Hervás, S. García-Yuste, M. I. López-Solera, A. Otero, A. R. Fernández-Pacheco, M. T. Tercero-Morales. Synthesis and Reactivity of New Niobocene Hydride-Stibine and Hydride-Stilbene Complexes. X-ray Crystal Structure of [Nb(η5-C5H4SiMe3)2(H)(trans-η2-C,C-PhCH═CHPh)]. Organometallics, 2013, 32, 862-868. DOI: 10.1021/om301171j
  42. R. Garcı́a-Álvarez, F. J. Suárez, J. Dı́ez, P. Crochet, V. Cadierno, A. Antiñolo, R. Fernández-Galán, F. Carrillo-Hermosilla. Ruthenium(II) Arene Complexes with Asymmetrical Guanidinate Ligands: Synthesis, Characterization, and Application in the Base-Free Catalytic Isomerization of Allylic Alcohols. Organometallics, 2012, 31, 8301-8311. DOI: 10.1021/om3009124
  43. R. Fernández-Galán, A. Antiñolo, F. Carrillo-Hermosilla, I. López-Solera, A. Otero, A. Serrano-Laguna, E. Villaseñor. Migratory Insertion Reactions in Asymmetrical Guanidinate-Supported Zirconium Complexes. Organometallics, 2012, 31, 8360-8369. DOI: 10.1021/om300942p
  44. R. Fernández-Galán, A. Antiñolo, F. Carrillo-Hermosilla, I. López-Solera, A. Otero, A. Serrano-Laguna, E. Villaseñor. New zirconium and zirconocene guanidinate complexes. J. Organomet. Chem., 2012, 711, 35-42. DOI: 10.1016/j.jorganchem.2012.03.023
  45. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, B. Menot, R. Fernández-Galán, E. Villaseñor, A. Otero. New Alkylimido Niobium Complexes Supported by Guanidinate Ligands: Synthesis, Characterization, and Migratory Insertion Reactions. Organometallics, 2012, 31, 1840-1848. DOI: 10.1021/om201192w
  46. A. Antiñolo, K. Dorani, S. García-Yuste, I. López-Solera, A. Otero, M. T. Tercero-Morales, G. Kovács, G. Ujaque, A. Lledós. Experimental and Theoretical Studies of the Hydrogenation of α,β-Unsaturated Acids by an 18e Hydride Carbonylniobocene Complex. Organometallics, 2012, 31, 5177-5184. DOI: 10.1021/om300510m
  47. A. Antiñolo, F. Carrillo-Hermosilla, V. Cadierno, J. García-Álvarez, A. Otero. Microwave-Assisted Meyer–Schuster Rearrangement of Propargylic Alcohols Catalyzed by the Oxovanadate Complex [V(O)Cl(OEt)2]. ChemCatChem, 2012, 4, 123-128. DOI: 10.1002/cctc.201100239
  48. C. Alonso-Moreno, A. Antiñolo, J. C. García-Martínez, S. García-Yuste, I. López-Solera, A. Otero, J. C. Pérez-Flores, M. T. Tercero-Morales.Molecular Structure of a Hydridoniobocene Complex [Nb(η5-C5H4SiMe3)2(H)3] and Its Use as Catalyst for the Ring-Opening Polymerization of Cyclic Esters. Eur. J. Inorg. Chem., 2012, 2012, 1139-1144. DOI: 10.1002/ejic.201101263
  49. R. Reguillo-Carmona, A. Antiñolo, S. García-Yuste, I. López-Solera, A. Otero. Lewis base character of the phosphorus atom in phosphanido-niobocene complexes. Synthesis of new early–early homo- and heterobimetallic entities. Dalton Trans., 2011, 40, 2622-2630. DOI: 10.1039/c0dt00865f
  50. J. Romero-Fernández, F. Carrillo-Hermosilla, A. Antiñolo, C. Alonso-Moreno, A. M. Rodríguez, I. López-Solera, A. Otero. Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines. Dalton Trans., 2010, 39, 6419-6425. DOI: 10.1039/c0dt00064g
  51. A. Antiñolo, S. García-Yuste, A. Otero, R. Reguillo-Carmona, M. T. Tercero-Morales. An easy and direct synthetic route to phosphamido niobocenes through nucleophilic attack of phosphide niobocene complexes on acyl halides. Comptes Rendus Chimie, 2010, 13, 929-934. DOI: 10.1016/j.crci.2010.03.018
  52. A. Antiñolo, S. García-Yuste, I. López Solera, A. Otero, J. C. Pérez-Flores, R. Reguillo-Carmona, E. Villaseñor, E. Santos, E. Zuidema, C. Bo. Reactions of alkynes with phosphido niobocenes: a combined experimental and theoretical study. Dalton Trans., 2010, 39, 1962-1971. DOI: 10.1039/b918298e
  53. C. Alonso-Moreno, F. Carrillo-Hermosilla, A. Garcés, A. Otero, I. López-Solera, A. M. Rodríguez, A. Antiñolo. Simple, Versatile, and Efficient Catalysts for Guanylation of Amines. Organometallics, 2010, 29, 2789-2795. DOI: 10.1021/om1003122