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  2. Organometallic Chemistry and Homogeneous Catalysis (QUIMORCA)
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Publications

2010-present

  1. D. Elorriaga, B. Parra-Cadenas, A. Antiñolo, F. Carrillo-Hermosilla, J. García-Álvarez. Combination of air/moisture/ambient temperature compatible organolithium chemistry with sustainable solvents: selective and efficient synthesis of guanidines and amidines. Green Chemistry, 2022, 24, 800-812. 10.1039/D1GC03393J
  2. P. J. Pacheco-Liñán, C. Alonso-Moreno, F. Carrillo-Hermosilla, A. Garzón-Ruiz, C. Martín, C. Sáez, J. Albaladejo and I. Bravo. Novel Fluorescence Guanidine Molecules for Selective Sulfate Anion Detection in Water Complex Samples over a Wide pH Range. ACS Sens. 2021, 6, 3224–3233. 10.1021/acssensors.1c00876
  3. Y. Rios Yepes, Á. Mesías-Salazar, A. Becerra, C. G. Daniliuc, A. Ramos, R. Fernández-Galán, A. Rodríguez-Diéguez, A. Antiñolo, F. Carrillo-Hermosilla and R. S. Rojas. Mono- and Dinuclear Asymmetric Aluminum Guanidinates for the Catalytic CO2 Fixation into Cyclic Carbonates. Organometallics 2021, 40, 2859-2869. DOI: 10.1021/acs.organomet.1c00319
  4. R. S. Rojas, K. Muñoz-Becerra, A. Toro-Labbé, A. Mesías-Salazar, I. Martínez, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, A. Ramos, C. G. Daniliuc, New guanidine-borane adducts: An experimental and theoretical approach. Inorg. Chim. Acta 2021, 518, 120217. DOI: 10.1016/j.ica.2020.120217
  5. E. Huergo, R. Fernández-Galán, A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, A. Rodríguez-Diéguez, D. García-Vivó. Reactivity of N-Phosphinoguanidines of the Formula (HNR)(Ph2PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from N-Phosphinoguanidinates to Phosphinimine-Amidinates. Inorg. Chem. 2020, 59, 15262-15275. DOI: 10.1021/acs.inorgchem.0c02224
  6. A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán. Ph2PCH2CH2B(C8H14) and Its Formaldehyde Adduct as Catalysts for the Reduction of CO2 with Hydroboranes. Inorg. Chem. 2020, 59, 9998-10012. DOI: 10.1021/acs.inorgchem.0c01152
  7. Y. Rios Yepes, J. Martínez, H. Rangel Sánchez, C. Quintero, M. C. Ortega-Alfaro, J. G. López-Cortés, C. G. Daniliuc, A. Antiñolo, A. Ramos, R. S. Rojas, R. Aluminum complexes with new non-symmetric ferrocenyl amidine ligands and their application in CO2 transformation into cyclic carbonates. Dalton Trans., 2020, 49, 1124-1134. DOI: 10.1039/C9DT03808F
  8. A. Mesias-Salazar, O. S. Trofymchuk, C. G. Daniliuc, A. Antiñolo, F. Carrillo-Hermosilla, F. M. Nachtigall, L. S. Santos, R. S. Rojas. Copper (II) as catalyst for intramolecular cyclization and oxidation of (1,4-phenylene)bisguanidines to benzodiimidazole-diylidenes. J. Catal., 2020, 382, 150-154. DOI: https://doi.org/10.1016/j.jcat.2019.12.002
  9. A. Antiñolo, S. García-Yuste, I. López-Solera, A. Otero, M. T. Tercero-Morales, F. Carrillo-Hermosilla. Reactivity studies on a trihydride niobocene complex towards α,β-Unsaturated carboxylic acids. J. Organomet. Chem., 2019, 897, 120-129. DOI: 10.1016/j.jorganchem.2019.06.006
  10. Á. Mesías-Salazar, J. Martínez, R. S. Rojas, F. Carrillo-Hermosilla, A. Ramos, R. Fernández-Galán, A. Antiñolo. Aromatic guanidines as highly active binary catalytic systems for the fixation of CO2 into cyclic carbonates under mild conditions. Catal. Sci. Technol., 2019, 9, 3879-3886. DOI: 10.1039/c9cy00667b
  11. A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, D. García-Vivó. 9-Borabicyclo[3.3.1]nonane: a metal-free catalyst for the hydroboration of carbodiimides, Chem. Commun., 2019, 55, 3073-3076. DOI: 10.1039/C9CC00593E
  12. R. Fernández-Galán, A. Ramos, E. Huergo, A. Antiñolo, F. Carrillo-Hermosilla, A. Rodríguez-Diéguez, D. García-Vivó. Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds. Chem. Commun., 2019, 55, 2809-2812. DOI: 10.1039/C9CC00432G
  13. A. Antiñolo, M. A. Esteruelas, C. García-Yebra, J. Martín, E. Oñate, A. Ramos. Reactions of an Osmium(IV)-Hydroxo Complex with Amino-Boranes: Formation of Boroxide Derivatives. Organometallics, 2019, 38, 310-318. DOI: 10.1021/acs.organomet.8b00727
  14. S. Moreno, A. Ramos, F. Carrillo-Hermosilla, A. Rodríguez-Diéguez, D. García-Vivó, R. Fernández-Galán, A. Antiñolo. Selective Three-Component Coupling for CO2 Chemical Fixation to Boron Guanidinato Compounds Inorg. Chem., 2018, 57, 8404-8413. DOI: 10.1021/acs.inorgchem.8b01068
  15. A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Gálan, A. Rodríguez-Diéguez, D. García-Vivó. Carbodiimides as catalysts for the reduction of CO2 with boranes. Chem. Commun., 2018, 54, 4700-4703. DOI: 10.1039/C8CC02139B
  16. P. J. Pacheco-Liñán, J. Fernández-Sainz, I. Bravo, A. Garzón-Ruiz, C. Alonso-Moreno, F. Carrillo-Hermosilla, A. Antiñolo, José Albaladejo. Guanidine Substitutions in Naphthyl Systems to Allow a Controlled Excited-State Intermolecular Proton Transfer: Tuning Photophysical Properties in Aqueous Solution. J. Phys. Chem. C, 2018, 122, 9363-9373. DOI: 10.1021/acs.jpcc.8b02576
  17. A. Martínez, S. Moreno-Blázquez, A. Rodríguez-Diéguez, A. Ramos, R. Fernández-Galán, A. Antiñolo, F. Carrillo-Hermosilla. Simple ZnEt2 as a catalyst in carbodiimide hydroalkynylation: structural and mechanistic studies. Dalton Trans., 2017, 46, 12923-12934. DOI: 10.1039/C7DT02700A
  18. A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, M. P. Montero-Rama, E. Villaseñor, A. Rodríguez-Diéguez, D. García-Vivó. Insertion reactions of small unsaturated molecules in the N-B bonds of boron guanidinates. Dalton Trans., 2017, 46, 10281-10299. DOI: 10.1039/C7DT02081C
  19. I. Posadas, C. Alonso-Moreno, I. Bravo, F. Carrillo-Hermosilla, A. Garzón, N. Villaseca, I. López-Solera, J. Albaladejo, V. Ceña. Synthesis, Characterization, DNA Interactions and Antiproliferative Activity on Glioblastoma of Iminopyridine Platinum (II) Chelate Complexes. J. Inorg. Biochem., 2017, 168, 46-54. DOI: 10.1016/j.jinorgbio.2016.11.032
  20. A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, M. P. Montero-Rama, A. Ramos, E. Villaseñor, R. S. Rojas, A. Rodríguez-Diéguez. Dialkylboron guanidinates: syntheses, structures and carbodiimide de-insertion reactions. Dalton Trans., 2016, 45, 15350-15363. DOI: 10.1039/C6DT02913B
  21. M. De Tullio, A. Hernán-Gómez, Z. Livingstone, W. Clegg, A. R. Kennedy, R. W. Harrington, A. Antiñolo, A. Martínez, F. Carrillo-Hermosilla, E. Hevia. Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines. Chem. Eur. J., 2016, 22, 17646-17656. DOI: 10.1002/chem.201602906
  22. A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, J. Martínez-Ferrer, C. Alonso-Moreno, I. Bravo, S. Moreno-Blázquez, M. Salgado, E. Villaseñor, J. Albaladejo. Tris(pentafluorophenyl)borane as an efficient catalyst in the guanylation reaction of amines. Dalton Trans., 2016, 45, 10717-10729. DOI: 10.1039/C6DT01237J
  23. Iván Bravo, Carlos Alonso-Moreno, Inmaculada Posadas, José Albaladejo, Fernando Carrillo-Hermosilla, Valentín Ceña, Andres Garzón, Isabel López-Solera, Laura Romero-Castillo. Phenyl-Guanidine Derivatives as Potential Therapeutic Agents for Glioblastoma Multiforme: Catalytic Syntheses, Cytotoxic Effects and DNA Affinity. RSC Advances, 2016, 6, 8267-8276. DOI: 10.1039/C5RA17920C
  24. J. Francos, P. J. González-Liste, L. Menéndez-Rodríguez, P. Crochet, V. Cadierno, J. Borge, A. Antiñolo, R. Fernández-Galán, F. Carrillo-Hermosilla. Half-Sandwich Guanidinate-Osmium(II) Complexes: Synthesis and Application in the Selective Dehydration of Aldoximes. Eur. J. Inorg. Chem., 2016, 393-402. DOI: 10.1002/ejic.201501221
  25. D. Nieto, S. Bruña, A. M. González-Vadillo, J. Perles, F. Carrillo-Hermosilla, A. Antiñolo, J. M. Padrón, G. B. Plata, I. Cuadrado. Catalytically Generated Ferrocene-Containing Guanidines as Efficient Precursors for New Redox-Active Heterometallic Platinum(II) Complexes with Anticancer Activity. Organometallics, 2015, 34, 5407-5417. DOI: 10.1021/acs.organomet.5b00751
  26. I. Bravo, C. Alonso-Moreno, F. Carrillo-Hermosilla, I. López-Solera, A. Antiñolo, J. Albaladejo. Toward the Prediction of Activity in the Ethylene Polymerisation of ansa-Bis(indenyl) Zirconocenes: Effect of the Stereochemistry and Hydrogenation of the Indenyl Moiety. ChemPlusChem, 2015, 80, 963-972. DOI: 10.1002/cplu.201500008
  27. L. Menéndez-Rodrı́guez, E. Tomás-Mendivil, J. Francos, P. Crochet, V. Cadierno, A. Antiñolo, R. Fernández-Galán,F. Carrillo-Hermosilla. Reactivity of the Dimer [{RuCl(μ-Cl)(η3:η3-C10H16)}2] (C10H16= 2,7-Dimethylocta-2,6-diene-1,8-diyl) toward Guanidines: Access to Ruthenium(IV) and Ruthenium(II) Guanidinate Complexes. Organometallics, 2015, 34, 2796-2809. DOI: 10.1021/acs.organomet.5b00070
  28. A. Antiñolo, S. García Yuste, A. Otero, A. Espinosa. Unusual Mechanism for the Reaction of a Niobocene HydrideComplex with Activated Alkynes. Experimental and DFT Studies. Organometallics, 2015, 34, 2695-2698. DOI: 10.1021/om5010989
  29. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, R. Fernández-Galán, E. Villaseñor. Mixed amido-/imido-/guanidinato niobium complexes: synthesis and the effect of ligands on insertion reactions. Dalton Trans., 2014, 43, 17434-17444. DOI: 10.1039/c4dt01975j
  30. A.R. Cabrera, E. Villaseñor, F. Werlinger, R. S. Rojas, M. Valderrama, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán. Grafting of the zirconium complexes [Zr(η5-C5H5){NC-amidine}Cl2] and [Zr(η5-C5H5)(NC-NacNac)Cl2] and the study of their behavior in ethylene polymerization. J. Mol. Cat. A., 391, 130-138. DOI: 10.1016/j.molcata.2014.04.017
  31. C. Alonso-Moreno, A. Antiñolo, F. Carrillo-Hermosilla, A. Otero. Guanidines: from classical approaches to efficient catalytic syntheses. Chem. Soc. Rev., 2014, 43, 3406-3425. DOI: 10.1039/c4cs00013g
  32. R. Fernández-Galán, J.-A. Navarro, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, E. Villaseñor. Preparation and Structural Studies of Non-Symmetric Guanidinate-Supported Zirconium Complexes. Aust. J. Chem., 2014, 67, 1063. DOI: 10.1071/ch14181
  33. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, R. Fernández-Galán, E. Villaseñor. Unexpected mild C-N bond cleavage mediated by guanidine coordination to a niobium iminocarbamoyl complex. Chem. Commun., 2013, 49, 8701-8703. DOI: 10.1039/c3cc44952a
  34. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, F. J. Suárez, I. López-Solera, R. Fernández-Galán, E. Villaseñor. Asymmetric niobium guanidinates as intermediates in the catalytic guanylation of amines. Dalton Trans., 2013, 42, 8223-8230. DOI: 10.1039/C3DT50477H
  35. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, R. Fernández-Galán, A. Serrano, E. Villaseñor. Synthesis, Characterization and Reactivity of New Dinuclear Guanidinate Diimidoniobium Complexes. Eur. J. Inorg. Chem., 2013, 2940-2946. DOI: 10.1002/ejic.201300025
  36. E. Villaseñor, R. Gutierrez-Gonzalez, F. Carrillo-Hermosilla, R. Fernández-Galán, I. López-Solera, A. R. Fernández-Pacheco, A. Antiñolo. Neutral Dimethylzirconocene Complexes as Initiators for the Ring-Opening Polymerization of ϵ-Caprolactone. Eur. J. Inorg. Chem., 2013, 2013, 1184-1196. DOI: 10.1002/ejic.201201096
  37. A. Antiñolo, J.-C. Pérez-Flores, M. J. Hervás, S. García-Yuste, M. I. López-Solera, A. Otero, A. R. Fernández-Pacheco, M. T. Tercero-Morales. Synthesis and Reactivity of New Niobocene Hydride-Stibine and Hydride-Stilbene Complexes. X-ray Crystal Structure of [Nb(η5-C5H4SiMe3)2(H)(trans-η2-C,C-PhCH═CHPh)]. Organometallics, 2013, 32, 862-868. DOI: 10.1021/om301171j
  38. R. Garcı́a-Álvarez, F. J. Suárez, J. Dı́ez, P. Crochet, V. Cadierno, A. Antiñolo, R. Fernández-Galán, F. Carrillo-Hermosilla. Ruthenium(II) Arene Complexes with Asymmetrical Guanidinate Ligands: Synthesis, Characterization, and Application in the Base-Free Catalytic Isomerization of Allylic Alcohols. Organometallics, 2012, 31, 8301-8311. DOI: 10.1021/om3009124
  39. R. Fernández-Galán, A. Antiñolo, F. Carrillo-Hermosilla, I. López-Solera, A. Otero, A. Serrano-Laguna, E. Villaseñor. Migratory Insertion Reactions in Asymmetrical Guanidinate-Supported Zirconium Complexes. Organometallics, 2012, 31, 8360-8369. DOI: 10.1021/om300942p
  40. R. Fernández-Galán, A. Antiñolo, F. Carrillo-Hermosilla, I. López-Solera, A. Otero, A. Serrano-Laguna, E. Villaseñor. New zirconium and zirconocene guanidinate complexes. J. Organomet. Chem., 2012, 711, 35-42. DOI: 10.1016/j.jorganchem.2012.03.023
  41. D. Elorriaga, F. Carrillo-Hermosilla, A. Antiñolo, I. López-Solera, B. Menot, R. Fernández-Galán, E. Villaseñor, A. Otero. New Alkylimido Niobium Complexes Supported by Guanidinate Ligands: Synthesis, Characterization, and Migratory Insertion Reactions. Organometallics, 2012, 31, 1840-1848. DOI: 10.1021/om201192w
  42. A. Antiñolo, K. Dorani, S. García-Yuste, I. López-Solera, A. Otero, M. T. Tercero-Morales, G. Kovács, G. Ujaque, A. Lledós. Experimental and Theoretical Studies of the Hydrogenation of α,β-Unsaturated Acids by an 18e Hydride Carbonylniobocene Complex. Organometallics, 2012, 31, 5177-5184. DOI: 10.1021/om300510m
  43. A. Antiñolo, F. Carrillo-Hermosilla, V. Cadierno, J. García-Álvarez, A. Otero. Microwave-Assisted Meyer–Schuster Rearrangement of Propargylic Alcohols Catalyzed by the Oxovanadate Complex [V(O)Cl(OEt)2]. ChemCatChem, 2012, 4, 123-128. DOI: 10.1002/cctc.201100239
  44. C. Alonso-Moreno, A. Antiñolo, J. C. García-Martínez, S. García-Yuste, I. López-Solera, A. Otero, J. C. Pérez-Flores, M. T. Tercero-Morales.Molecular Structure of a Hydridoniobocene Complex [Nb(η5-C5H4SiMe3)2(H)3] and Its Use as Catalyst for the Ring-Opening Polymerization of Cyclic Esters. Eur. J. Inorg. Chem., 2012, 2012, 1139-1144. DOI: 10.1002/ejic.201101263
  45. R. Reguillo-Carmona, A. Antiñolo, S. García-Yuste, I. López-Solera, A. Otero. Lewis base character of the phosphorus atom in phosphanido-niobocene complexes. Synthesis of new early–early homo- and heterobimetallic entities. Dalton Trans., 2011, 40, 2622-2630. DOI: 10.1039/c0dt00865f
  46. J. Romero-Fernández, F. Carrillo-Hermosilla, A. Antiñolo, C. Alonso-Moreno, A. M. Rodríguez, I. López-Solera, A. Otero. Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines. Dalton Trans., 2010, 39, 6419-6425. DOI: 10.1039/c0dt00064g
  47. A. Antiñolo, S. García-Yuste, A. Otero, R. Reguillo-Carmona, M. T. Tercero-Morales. An easy and direct synthetic route to phosphamido niobocenes through nucleophilic attack of phosphide niobocene complexes on acyl halides. Comptes Rendus Chimie, 2010, 13, 929-934. DOI: 10.1016/j.crci.2010.03.018
  48. A. Antiñolo, S. García-Yuste, I. López Solera, A. Otero, J. C. Pérez-Flores, R. Reguillo-Carmona, E. Villaseñor, E. Santos, E. Zuidema, C. Bo. Reactions of alkynes with phosphido niobocenes: a combined experimental and theoretical study. Dalton Trans., 2010, 39, 1962-1971. DOI: 10.1039/b918298e
  49. C. Alonso-Moreno, F. Carrillo-Hermosilla, A. Garcés, A. Otero, I. López-Solera, A. M. Rodríguez, A. Antiñolo. Simple, Versatile, and Efficient Catalysts for Guanylation of Amines. Organometallics, 2010, 29, 2789-2795. DOI: 10.1021/om1003122