Principal

Producción Volver al web de la Universidad
 

Perfil del Grupo
Líneas de trabajo
Oferta tecnológica
Proyectos
Producción
Colaboraciones
Enlaces

 

  • Artículos en revistas internacionales, en los últimos años
1. On the Search for NNO-Donor Enantiopure Scorpionate Ligands and Their Coordination to Group 4 Metals
By Otero, Antonio; Fernandez-Baeza, Juan; Tejeda, Juan; Lara-Sanchez, Agustin; Sanchez-Molina, Margarita; Franco, Sonia; Lopez-Solera, Isabel; Rodriguez, Ana M.; Sanchez-Barba, Luis F.; Morante-Zarcero, Sonia; et al
From Inorganic Chemistry (Washington, DC, United States), ACS ASAP. Language: English, Database: CAPLUS
The prepn. of new chiral bis(pyrazol-1-yl)methane-based NNO-donor scorpionate ligands in the form of the lithium derivs. [Li(bpzb)(THF)] [1; bpzb = 1,1-bis(3,5-dimethylpyrazol-1-yl)-3,3-dimethyl-2-butoxide] and [Li(bpzte)(THF)] [2; bpzte = 2,2-bis(3,5-dimethylpyrazol-1-yl)-1-p-tolylethoxide] or the alc. ligands (bpzbH) (3) and (bpzteH) (4) has been carried out by 1,2-addn. reactions with trimethylacetaldehyde or p-tolualdehyde.  The sepn. of a racemic mixt. of the alc. ligand 3 has been achieved and gave an enantiopure NNO alc.-scorpionate ligand in three synthetic steps: (i) 1,2-addn. of the ...
 
 2. Well-defined regioselective iminopyridine rhodium catalysts for anti-Markovnikov addition of aromatic primary amines to 1-octyne
By Alonso-Moreno, Carlos; Carrillo-Hermosilla, Fernando; Romero-Fernandez, Javier; Rodriguez, Ana M.; Otero, Antonio; Antinolo, Antonio
From Advanced Synthesis & Catalysis (2009), 351(6), 881-890. Language: English, Database: CAPLUS
A series of cationic rhodium(I) complexes of the type [Rh(N-N)(COD)][BPh4], contg. the following iminopyridine-based bidentate nitrogen donor ligands (N-N): 2,6-diisopropyl-N-[1-(pyridin-2-yl)ethylidene]aniline (dipea, 1), 2,6-dimethyl-N-[1-(pyridin-2-yl)ethylidene]aniline (dmpea, 2), 2,4,6-trimethyl-N-[1-(pyridin-2-yl)ethylidene]aniline (tmpea, 3) and 2,6-diisopropyl-N-[1-(4-methylpyridin-2-yl)ethylidene]aniline] (dipmpea, 4), were synthesized and fully characterized.  The intermol. hydroamination of a terminal alkyne, such as 1-octyne, with primary arom. amines in the presence of these catio...
 
3. New alkenyl-substituted group 4 C-ansa-metallocene complexes. Reactivity of the substituent at the carbon ansa bridge
By Antinolo, Antonio; Fernandez-Galan, Rafael; Molina, Noelia; Otero, Antonio; Rivilla, Ivan; Rodriguez, Ana M.
From Journal of Organometallic Chemistry (2009), 694(13), 1959-1970. Language: English, Database: CAPLUS
The allyl-substituted group 4 metal complexes [M{(R)CH(η5-C5Me4)(η5-C5H4)}Cl2] [M = Ti, R = CH2CH=CH2, (2); R = CH2C(CH3)=CH2 (3); M = Zr, R = CH2CH=CH2 (4), R = CH2C(CH3)=CH2 (5)] have been synthesized by the reaction of allyl ansa-magnesocene derivs. and the tetrachloride salts of the corresponding transition metal.  The dialkyl complexes [M(R)CH(η5-C5Me4) (η5-C5H4)R'2] [M = Ti, R = CH2=CHCH2, R' = Me (6), R' = CH2Ph (7); R = CH2C(CH3)=CH2, R' = Me (8), R' = CH2Ph (9); M = Zr, R = CH2CH=CH2, R' = Me (10), R' = CH2Ph (11); R = CH2C(CH3)=CH2, R' = Me (12), R' = CH2Ph (13)] have been synthesize...
 
 4. Reactivity of a Super-Electron-Rich Olefin Derived from Cyclam
By Lappert, Michael F.; Alvarez, Santiago; Aullon, Gabriel; Fandos, Rosa; Otero, Antonio; Rodriguez, Ana; Rojas, Sergio; Terreros, Pilar
From European Journal of Inorganic Chemistry (2009), (13), 1851-1860. Language: English, Database: CAPLUS
A series of new compds. has been synthesized from an electron-rich olefin derived from cyclam (A).  Thus, A reacts with oxygen gas to give the syn-bis(urea) 1 and with sulfur to yield the anti-bis(thiourea) 2.  The reaction of A with triflic acid furnishes the bis(imidazolium) triflate 3, which gives the monoprotonated imidazolium salt 4 upon treatment with sodium tetraphenylborate in water.  Theor. calcns. (DFT) predict the diprotonated species to be energetically disfavored, thus demonstrating the importance of hydrogen-bonding interactions.  Treatment of compd. 3 with silver oxide affords t...
 
5. Hybrid scorpionate/cyclopentadienyl titanium and zirconium complexes with alkoxide and imido ligands
By Otero, Antonio; Fernandez-Baeza, Juan; Antinolo, Antonio; Tejeda, Juan; Lara-Sanchez, Agustin; Sanchez-Barba, Luis F.; Sanchez-Molina, Margarita; Bo, Carles; Urbano-Cuadrado, Manuel
From Inorganica Chimica Acta (2009), 362(8), 2909-2914. Language: English, Database: CAPLUS
The reactivity of hybrid scorpionate/cyclopentadienyl ligand-contg. trichloride zirconium complexes [ZrCl3(bpzcp)] (1) [bpzcp = 2,2-bis(3,5-dimethylpyrazol-1-yl)-1,1-diphenylethylcyclopentadienyl] and [ZrCl3(bpztcp)] (2) [bpztcp = 2,2-bis(3,5-dimethylpyrazol-1-yl)-1-tert-butylethylcyclopentadienyl] toward several lithium alkoxides has been carried out.  Thus, alkoxide-contg. complexes [ZrCl2(OR)(bpzcp)] (R = Me, 3; Et, 4; iPr, 5; (R)-2-Bu, 6), [ZrCl2(OR)(bpztcp)] (R = Me, 7; Et, 8; iPr, 9; (R)-2-Bu, 10) and [Zr(OR)3(bpztcp)] (R = Et, 11; iPr, 12) were prepd. by deprotonation of the appropriate...
 
 6. Homogeneous and supported bis(imino)pyridyl vanadium(III) catalysts
By Romero, Javier; Carrillo-Hermosilla, Fernando; Antinolo, Antonio; Otero, Antonio
From Journal of Molecular Catalysis A: Chemical (2009), 304(1-2), 180-186. Language: English, Database: CAPLUS
Bis(imino)piridyl vanadium(III) complexes have been synthesized and characterized by NMR, FT-IR and UV-vis spectroscopy.  The activation reaction of these complexes in soln. with methylalumoxane (MAO) was followed by UV-vis spectroscopy.  The reactions of the complexes with the surface of silica were monitored by FT-IR spectroscopy.  The resulting materials were activated with MAO or triisobutylaluminium (TIBA) and the catalytic systems were evaluated in the polymn. of ethylene.  Characterization of the catalysts was accomplished by elemental anal. and by UV-vis spectroscopy.  The effects caus...
 
7. A new titanium alkoxide-thiolate complex as a versatile heterofunctional metalloligand
By Fandos, Rosa; Otero, Antonio; Rodriguez, Ana; Terreros, Pilar; Aullon, Gabriel; Alvarez, Santiago
From European Journal of Inorganic Chemistry (2009), (8), 1079-1085. Language: English, Database: CAPLUS
The titanium complex [TiCp*(OSBz)(OBzSH)] (1) has been synthesized by reaction of [TiCp*(Me)3] (Cp* = η5-C5Me5) with 2-mercaptobenzyl alc. (H2OSBz).  The reaction of complex 1 with H2O gives the dinuclear oxo-bridged complex [{TiCp*(OSBz)}2(μ-O)] (2).  Complex 1 reacts with [M(μ-OH)(cod)]2 (M = Rh, Ir) to yield the early-late heterobimetallic complexes [TiCp*(OSBz)2M(cod)] {M = Rh (3); Ir (4)}.  Carbon monoxide easily replaces the cod ligand in 3 and 4, which leads to the corresponding dicarbonyl derivs. [TiCp*(OSBz)2M(CO)2] {M = Rh (5); Ir (6)}.  Compd. 5 reacts with PPh3 to yield the monocar...
 
8. Ring-opening polymerization of cyclic esters by an enantiopure heteroscorpionate rare earth initiator
By Otero, Antonio; Fernandez-Baeza, Juan; Lara-Sanchez, Agustin; Alonso-Moreno, Carlos; Marquez-Segovia, Isabel; Sanchez-Barba, Luis F.; Rodriguez, Ana M.
From Angewandte Chemie, International Edition (2009), 48(12), 2176-2179. Language: English, Database: CAPLUS
With a sting in its tail: An enantiopure neodymium complex acts as an efficient single-site initiator for the controlled ring-opening polymn. of rac-lactide, forming isotactic polyester.  The heteroscorpionate complex was characterized spectroscopically and by X-ray diffraction.
 
9. Insertion reactions of isothiocyanates into the Nb-P bond of phosphide-niobocene complexes
By Antinolo, Antonio; Garcia-Yuste, Santiago; Otero, Antonio; Reguillo-Carmona, Rebeca
From European Journal of Inorganic Chemistry (2009), (4), 539-544. Language: English, Database: CAPLUS
The reaction of the niobocene complex [Nb(η5-C5H4SiMe3)2(PPh2)(L)] {L = CO (1), CNXylyl (2), and CNCy (3)} with isothiocyanates RNCS (R = tBu or Ph) yielded new derivs. [Nb(η5-C5H4SiMe3)2{κ1-S-SC(PPh2)(=NR)}(L)] {R = tBu, L = CO (4), CNXylyl (5); R = Ph, L = CO (6), CNXylyl (7), CNCy (8)} by the insertion of the isothiocyanate group into the niobium-phosphorus bond of the phosphide ligand.  Dinuclear complexes were also obtained by the reaction of complexes 1-3 with phenyldiisothiocyanate {1,4-(SCN)2C6H4} to yield [{Nb(η5-C5H4SiMe3)2(L)}2 {μ-(κ1-S-1,4-SC{PPh2}{=N})2(C6H4)}] {L = CO (9), CNXyly...
 
10. Synthesis, characterization and applications in ethylene polymerization of asymmetric ansa-titanocene complexes. Molecular structure of [Ti{Me2Si(η5-C5Me4)(η5-C5H3 iPr)}Cl2]
By Gomez-Ruiz, Santiago; Garces, Andres; Prashar, Sanjiv; Fajardo, Mariano; Antinolo, Antonio; Otero, Antonio
From Inorganica Chimica Acta (2009), 362(4), 1042-1046. Language: English, Database: CAPLUS
The ansa-titanocene complexes, [Ti{Me2Si(η5-C5Me4)(η5-C5H3R)}Cl2] (R = Me (5), iPr (6), tBu (7), SiMe3 (8)), were obtained from the reaction of Li2{Me2Si(C5Me4)(C5H3R)} (R = Me (1), iPr (2), tBu (3), SiMe3 (4)) with [TiCl4(THF)2], resp.  Compds. 5-8 have been tested as catalysts in the polymn. of ethylene and compared with the ansa-titanocene complexes [Ti{Me2Si(η5-C5H4)2}Cl2] and [Ti{Me2Si(η5-C5Me4)(η5-C5H4)}Cl2].  The resulting polyethylene showed mol. wts. of about 200 000 g mol-1 and polydispersity values of approx. 3.  In addn., the mol. structure of 6 has been detd. by single crystal X-r...
 
 11. Synthesis, characterization and compared reactivity of asymmetrical ansa-metallocenes
By Alonso-Moreno, Carlos; Sancho, Jose; Carrillo-Hermosilla, Fernando; Otero, Antonio; Antinolo, Antonio; Lopez-Solera, Isabel
From Inorganic Chemistry Communications (2009), 12(2), 184-186. Language: English, Database: CAPLUS
Rac and meso ansa-zirconocenes [Zr{1-Me2Si(3-R-(η5-C9H5))(3-R'-(η5-C9H5))}Cl2] (R = Et, R' = H; R = Pr, R' = H; and R = Et, R' = Pr) 4-9 have been prepd. by the reaction of ZrCl4 with the corresponding dilithiated derivs. from the ligands {1-Me2Si(3-R-(η5-C9H5))(3-R'-(η5-C9H5))} (R = Et, R' = H 1; R = Pr, R' = H 2; and R = Et, R' = Pr 3) in di-Et ether/toluene at -78 °C.  The mol. structure of rac [Zr{1-Me2Si(3-Et-(η5-C9H5))(3-Pr-(η5-C9H5))}Cl2] 8 has been detd. by single crystal X-ray diffraction studies, which show a pseudotetrahedral environment formed by the two chlorine ligands and two η5...
 
 12. Can related pyridine-alkoxide titanium complexes adopt different geometries? A combined experimental and theoretical study
By Fandos, Rosa; Gallego, Beatriz; Lopez-Solera, Maria Isabel; Otero, Antonio; Rodriguez, Ana; Ruiz, Maria Jose; Terreros, Pilar; van Mourik, Tanja
From Organometallics (2009), 28(5), 1329-1335. Language: English, Database: CAPLUS
Titanium half-sandwich pentamethylcyclopentadienyl complexes with pincer 2,6-pyridinedimethanolato and chelate 2-pyridinemethanolato ligands were prepd. by alcoholysis of Cp*TiX3 (X = Me, Cl) with the corresponding ligands; the prepd. complexes feature both trigonal-bipyramidal and more common piano-stool geometries.  Reaction of Cp*TiX3 (X = Me, Cl) with 1,3-(HOCH2)2C5H3N gave a series of new titanium half-sandwich pyridine-alkoxide complexes, [Cp*TiX{2,6-(OCH2)2py-κ3O,N,O}] (1, 2; X = Me, Cl), [Cp*Ti{2,6-(OCH2)py(CH2OH)-κO}{2,6-(OCH2)2py-κ3O,N,O}] (3), [TiCp*Me2{2-(OCH2)py-κ1O}] (4), [TiCp*M...
 
13. Recent advances in the design and coordination chemistry of heteroscorpionate ligands bearing stereogenic centres
By Otero, Antonio; Fernandez-Baeza, Juan; Lara-Sanchez, Agustin; Tejeda, Juan; Sanchez-Barba, Luis Fernando
From European Journal of Inorganic Chemistry (2008), (34), 5309-5326. Language: English, Database: CAPLUS
This review concerns the recent studies carried out by our research group and others aimed at the design of heteroscorpionate ligands based on bis(pyrazol-1-yl)methane-contg. stereogenic centers.  The capability of these systems to stabilize chiral complexes from early to late transition metals, through their behavior as multidentate hybrid ligands, is also described.
 
14. Oxo and Hydroxo Organometallic Complexes of Tantalum: Soluble Molecular Models of Tantalum Oxide
By Conde, Ana; Fandos, Rosa; Otero, Antonio; Rodriguez, Ana
From Organometallics (2008), 27(23), 6090-6095. Language: English, Database: CAPLUS
The tantalum complex [TaCp*Cl2{2,6(OOC)2py-κ2O,O}] (1) has been synthesized by reaction of [TaCp*Cl4], Cp* = η5-C5Me5, with 2,6-pyridinedicarboxylic acid.  Complex 1 reacts with AgOTf, OTf = trifluoromethylsulfate, to yield the new tantalum carboxylate deriv. [TaCp*Cl(OTf){2,6(OOC)2py-κ2O,O}] (2) or with KOH to render the dinuclear oxo compd. [TaCp*(μ-O){2,6(OOC)2py-κ2O,O}]2 (3).  The reaction of 3 with H2O and HOTf gives the dinuclear hydroxo deriv. [{TaCp*{2,6(OOC)2py-κ2O,O}}2(μ-OH)3](OTf) (5).  The structures of complexes 1, 2, 3, and 5 have been established by x-ray diffraction methods.
 
 15. Preparation, Characterization, and Reactivity of Tantalum Complexes Containing Tridentate Bis(phenolato) [OSO]-Type Ligands
By Fandos, Rosa; Fernandez-Gallardo, Jacob; Lopez-Solera, Maria Isabel; Otero, Antonio; Rodriguez, Ana; Ruiz, Maria Jose; Terreros, Pilar
From Organometallics (2008), 27(18), 4803-4809. Language: English, Database: CAPLUS
New Ta-tbcp [tbcp = 2,2'-thiobis(4,6-dichlorophenolato)] and Ta-tbop [tbop = 2,2'-thiobis(6-tert-octylphenolato)] complexes [TaCp*Cl2(κ3-tbop)] (1), [TaCp*Cl2(κ3-tbcp)] (2), [TaCp*Me2(κ3-tbop)] (3), [TaCp*Me2(κ3-tbcp)] (4), [TaCp*Me(κ3-tbop)(OTf)] (OTf = triflate) (5), [TaCp*Me(κ3-tbcp)(OTf)] (6), [TaCp*(κ3-tbop)(OTf)2] (7), and [TaCp*(κ3-tbcp)(OTf)2] (8) were synthesized.  Insertion processes into the Me groups of complex 3 were not obsd. upon reaction with CO or isocyanides.  In contrast, complex 4 reacted slowly with 1 equiv of xylyl isocyanide (xylyl = 2,6-dimethylphenyl) or tert-Bu isocya...
 
16. Synthesis and reactivity of monocyclopentadienyltantalum(V) siloxide complexes
By Conde, Ana; Fandos, Rosa; Otero, Antonio; Rodriguez, Ana; Terreros, Pilar
From European Journal of Inorganic Chemistry (2008), (19), 3062-3067. Language: English, Database: CAPLUS
The new tantalum siloxide complex [TaCp*Me3(OSiPh3)] (1; Cp* = η5-C5Me5) has been synthesized.  The reaction of complex 1 with isocyanides yields the resp. azatantalacyclopropanes [TaCp*(η2-Me2CNxylyl)Me(OSiPh3)] (2; xylyl = 2,6-dimethylphenyl) and [TaCp*(η2-Me2CNtBu)Me(OSiPh3)] (3).  The mol. structure of complex 2 has been established by X-ray diffraction.  Complex 2 reacts with a second mol-equiv. of 2,6-xylyl isocyanide to yield [TaCp*(Nxylyl)[N(xylyl)CMe=CMe2)(OSiPh3)] (4).  The reaction of 1 with carbon monoxide gives [TaCp*(O)(OCMe=CMe2)(OSiPh3)] (5), whereas 1 reacts with B(C6F5)3 to g...
 
17. Nitric oxide binding and photodelivery based on ruthenium(II) complexes of 4-arylazo-3,5-dimethylpyrazole
By Ortiz, Mayreli; Torrens, Mabel; Mola, Jose L.; Ortiz, Pedro J.; Fragoso, Alex; Diaz, Alicia; Cao, Roberto; Prados, Pilar; de Mendoza, Javier; Otero, Antonio; et al
From Dalton Transactions (2008), (27), 3559-3566. Language: English, Database: CAPLUS
Two fluorescent ligands, 3,5-dimethyl-4-(6'-sulfonylammonium-1'-azonaphthyl)pyrazole (dmpzn, 1) and 3,5-dimethyl-4-(4'-N,N'-dimethylaminoazophenyl)pyrazole (dmpza, 2) were obtained by condensation of ketoenolic derivs. with hydrazine.  1 And 2 formed the novel dinuclear complexes [(H2O)3ClRu(μ-L)2RuCl(H2O)3] (3 or 4) and [(H2O)(NO)Cl2Ru(μ-L)2RuCl2(NO)(H2O)] (6 or 7) (L = 1 or 2, resp.) which were characterized by IR, NMR and elemental anal.  The nitrosyl complexes were prepd. by bubbling purified nitric oxide through MeOH solns. of the corresponding Ru(II) chloro deriv. or by reaction of the a...
 
18. Versatile Scorpionates and New Developments in the Denticity Changes of NNCp Hybrid Scorpionate/Cyclopentadienyl Ligands in Sc and Y Compounds: From κ1-Nη5-Cp to κ2-NNη5-Cp
By Otero, Antonio; Fernandez-Baeza, Juan; Lara-Sanchez, Agustin; Antinolo, Antonio; Tejeda, Juan; Martinez-Caballero, Emilia; Marquez-Segovia, Isabel; Lopez-Solera, Isabel; Sanchez-Barba, Luis F.; Alonso-Moreno, Carlos
From Inorganic Chemistry (Washington, DC, United States) (2008), 47(11), 4996-5005. Language: English, Database: CAPLUS
Reaction of hybrid scorpionate/cyclopentadienyl ligands as the Li derivs. [Li(bpzcp)(THF)] [bpzcp = 2,2-bis(3,5-dimethylpyrazol-1-yl)-1,1-diphenylethylcyclopentadienyl], [Li(bpztcp)(THF)] [bpztcp = 2,2-bis(3,5-dimethylpyrazol-1-yl)-1-tert-butylethylcyclopentadienyl], and the in situ-generated Li(bpzpcp) [bpzpcp = 2,2-bis(3,5-dimethylpyrazol-1-yl)-1-phenylethylcyclopentadienyl] with MCl3(THF)3 (M = Sc, Y) afforded the group 3 halide compds. [MCl2(bpzcp)(THF)] (M = Sc (1, 86% yield); Y (2, 90%)), [MCl2(bpztcp)(THF)] (M = Sc (3, 85%); Y (4, 80%)), and [MCl2(bpzpcp)(THF)] (M = Sc (5, 78%); Y (6, 8...
 
19. Heterocycle-substituted indenes as precursors for supported zirconocene catalysts
By Saez, Pedro J. Aragon; Carrillo-Hermosilla, Fernando; Villasenor, Elena; Otero, Antonio; Antinolo, Antonio; Rodriguez, Ana M.
From European Journal of Inorganic Chemistry (2008), (2), 330-337. Language: English, Database: CAPLUS
The indene ligands {1-C9H7R} [R = C2H4(C4H7O2) (1), C2H4(C3H5O2) (2), CH2(C5H9O) (3)] were prepd. by alkylation of indene and used to prep. the SiMe2-bridged indenylcyclopentadiene ligands {Me2Si(3-C9H6R)(C5Me4H)} [R = C2H4(C4H7O2) (4), CH2(C5H9O) (5)].  Bis(indenyl)- and ansa-indenylcyclopentadienyl zirconocenes [Zr{1-η5-C9H6R}2Cl2] {R = C2H4(C4H7O2) (6), C2H4(C3H5O2) (7), CH2(C5H9O) (8)} and [Zr{Me2Si(3-η5-C9H5R)(η5-C5Me4)}Cl2] {R = C2H4(C4H7O2) (9), CH2(C5H9O) (10)} were prepd. by the reaction of ZrCl4 with the appropriate mono- or dilithium salts of 1-5.  The mol. structure of [Zr{Me2Si(3-...
 
20. Discrete heteroscorpionate lithium and zinc alkyl complexes. Synthesis, structural studies, and ROP of cyclic esters
By Alonso-Moreno, Carlos; Garces, Andres; Sanchez-Barba, Luis F.; Fajardo, Mariano; Fernandez-Baeza, Juan; Otero, Antonio; Lara-Sanchez, Agustin; Antinolo, Antonio; Broomfield, Lewis; Lopez-Solera, M. Isabel; et al
From Organometallics (2008), 27(6), 1310-1321. Language: English, Database: CAPLUS
The reaction of bis(3,5-di-tert-butylpyrazol-1-yl)methane (bdtbpzm) with BuLi and carbodiimide derivs., namely, N,N'-diisopropyl and 1-tert-butyl-3-Et carbodiimides, gives rise to the new sterically hindered Li acetamidinate [Li(tbptamd)(THF)] (1, tbptamd = N-ethyl-N'-tert-butyl-bis(3,5-di-tert-butylpyrazol-1-yl)acetamidinate, 86% yield) and [Li(pbptamd)(THF)] (2, pbptamd = N,N'-diisopropyl-bis(3,5-di-tert-butylpyrazol-1-yl)acetamidinate, 88%).  Subsequent hydrolysis of 1 and 2, and the recently reported heteroscorpionate Li salts [Li(tbpamd)(THF)] (tbpamd = N-ethyl-N'-tert-butyl-bis(3,5-dimet...
 
 

 

  • Patentes

 

AUTORES:C.Alonso,A.Antiñolo,F.Carrillo-Hermosilla,A.Otero, A. Antiñolo, J.Sancho

TITULO:Catalysts Compositions for the Polymerization and Copolymerization of Alpha-Olefins.

REFERENCIA: EP Patent 04380249.5.

ARRIBA

 

 

Envíe un mensaje a Fernando.Carrillo@uclm.es con preguntas o comentarios sobre este sitio Web.
Copyright © 2004 GRUPO DE QUÍMICA ORGANOMETÁLICA Y CATÁLISIS
Última modificación: 26 de mayo de 2009